News reports (see here and here
for instance) out of Wichita, KS today
described a ‘nitrogen explosion’ at an aircraft manufacturing facility. A security
video from a nearby facility shows the rapidly expanding vapor cloud and
flying debris. As many as 14 people have apparently been injured, but no
fatalities were reported.
Incident
Reports indicate that a 3” liquid nitrogen line ruptured
inside of the plant. No fires were reported. The resulting incident also
damaged a nearby liquid nitrogen storage tank. Due to the holidays and the
resulting reduced staffing, no one was near the site where the rupture occurred.
Commentary
While the expanding vapor cloud and flying debris looked
impressive and caused significant amounts of damage, what happened cannot
really be called an explosion since there was no detonation or fire associated
with the incident. What happened was that cryogenic (very cold) liquid nitrogen
escaped containment when the 3” line ruptured. As the liquid entered the atmosphere
it rapid warmed and boiled. The liquid expanded into a vapor cloud with 694
times the volume previously experienced in the liquid state.
This rapid expansion during the phase change caused an area
of high pressure that was lightly contained by the walls of the building. As
the pressure rapidly rose, the walls were no longer able to contain the
pressure and were blown outwards.
Neither liquid nitrogen nor nitrogen gas are chemically reactive
enough (in fact they are generally considered to be inert, or non-reactive) to
cause an explosion. If a similar volume of a chemically reactive substance were
to explode a large flame wall and much more damage would have resulted.
Having said that, situations such as this are very dangerous
and significant damage was done to the building and people were certainly
injured. What was not noted in any of the articles that I have seen was that there
was also a potential risk for asphyxiation near the leak as the expanding
nitrogen cloud displaced oxygen from the immediate area. There was also a
potential for severe cold injuries in the immediate area of the leak. From the
articles that I have seen it does not appear that anyone was near enough to the
initial leak for these to have been a problem.
The white cloud seen in the incident photos and videos was
not actually a nitrogen cloud. Nitrogen is colorless and odorless (and actually
makes up about 78% of the atmosphere). The visible vapor cloud is water in the
atmosphere that has been super cooled by the still very cold nitrogen gas to
form a cloud.
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