Recent reports about the possible use of chemical weapons in
an attack on Mariupol (see here for example).
The specter of chemical warfare always raises humanitarian concerns, but a close
reading of these reports raises the potential of another concern, unintentional
chemical warfare.
Background
Back in 1988 I wrote an article for the US Army Chemical
Review on “Modern Chemical Warfare – Complicated by a Long List of Toxic
Chemicals”. In that article I wrote about the problems associated with warfare
in and around chemical facilities. Attacks on such facilities could easily
result in the release of toxic chemicals that could have unintended
consequences on the battlefield. The worst result, beyond the possibility of
needless deaths and injuries in a combat zone, would be one side or the other
mistaking an industrial chemical release for an attack with chemical weapons.
For example, by long-standing US policy dating back to Ronald
Reagan, if American forces are attacked with chemical weapons, the US could
consider that an attack with weapons of mass destruction and reply in kind. The
only problem with that is that the only weapons of mass destruction in our
arsenal are nuclear weapons. Thus, we could see a situation arise where an
attack on an industrial facility defended by US forces could result in the release
of toxic chemicals and the commander on the scene could assume and report that
the resulting casualties were the result of a chemical weapons attack. In the
fog of war, such a report could potentially result in the release of tactical
nuclear weapons.
Or, say a world leader says that “if chemical weapons are
used in this conflict, we will intervene…”, then an industrial chemical release
could lead to a wider conflict.
The Reported Attack
The ‘attack’ that reportedly took place was described in the
BBC article like
this:
“One injured man described a "sweet-tasting" white
smoke covering an area of the plant after an explosion. Another said he felt
immediately unable to breathe and had collapsed with ‘cotton legs’.”
Obviously, both men survived the ‘chemical attack’. Now the
Russian military has had a large number of problems during this attack on Ukraine,
but I would be very surprised to hear that their chemical weapons did not work.
They have a long history back through the Soviet days of developing and producing
chemical weapons. So, if there were a Russian chemical attack on Ukrainian
forces, I would expect to hear about a large number of casualties.
The attack took place at the Azovstal metals plant outside
of the city. I’m not sure what kind of metals processing takes place there, but
many such plants use strong acids like nitric acid and sulfuric acid for metal
cleaning. White steam clouds are released when these acids react with water or even
moist air. A wide variety of industrial chemicals interfere with breathing. One
of the most common is cryogenic Nitrogen. Nitrogen is not toxic, but if the
concentration is too high, there would not be enough oxygen present. People
would pass out but would not die if the cloud blew through the area and an
adequate oxygen supply became available quickly enough.
Other industries would have different chemical hazards. An
interesting look at some of the chemicals associated with different industries
can be found on the Chemical Facility Anti-Terrorism Standards (CFATS) website. This page provides a
series of Industry Fact Sheets discussing what DHS chemicals of interest (COI)
are used by various non-chemical industry groups. They are certainly not
comprehensive lists of chemicals used, but they do show how wide spread chemical
use is in modern manufacturing environments.
Conclusion
To my mind, with my background in both the military and
chemical manufacturing, this attack does not sound like a deliberate chemical
attack. It sounds like the inevitable result of an attack on an industrial
facility that uses hazardous chemicals on a routine basis. Tossing artillery
rounds indiscriminately at such a facility is asking for a chemical release
that might be mistaken for the use of a chemical weapon.
Anyone defending such a facility had better be prepared to
conduct defensive operations in a chemical environment, with all of the difficulties
that that entails.