Showing posts with label RMP. Show all posts
Showing posts with label RMP. Show all posts

Thursday, January 22, 2026

OMB Approves EPA Accidental Chemical Release NPRM

Yesterday the OMB’s Office of Information and Regulatory Affairs (OIRA) announced that it had approved a notice of proposed rulemaking (NPRM) from the EPA on “Accidental Release Prevention Requirements: Risk Management Programs Under the Clean Air Act; Common Sense Approach to Chemical Accident Prevention ”. This rulemaking was submitted to OIRA on September 29th, 2025.

According to the listing for this rulemaking in the Spring 2025 Unified Agenda:

“The U.S. Environmental Protection Agency (EPA) is initiating a new rulemaking to reconsider the current Risk Management Program (RMP) rule requirements. The agency is providing notice of this proposed rulemaking, which will align with agency priorities to ensure clean air, land, and water for every American; restore American energy dominance; and promote cooperative federalism and cross-agency partnership while reducing regulatory burden on facilities.”

Interestingly, the Spring 2025 Unified Agenda suggests that this NPRM would be published in August 2025, and the Final Rule would be published in January 2026. Since the Spring 2025 Unified Agenda was not published until September 2025, that schedule was patently wrong. While this Administration has been fighting self-inflicted personnel issues, particularly in the EPA, and has been pursuing an aggressive regulatory agenda (deregulation still requires regulatory actions), these agenda delays also reflect on the inertia of the federal government; it is hard to get something this large moving in a new direction. As a cautionary note, it takes just as long to stop undesired actions.

NOTE: OIRA approved this NPRM ‘consistent with change'. It is never clear in these announcement how extensive those changes are, so it is difficult to predict how soon EPA will get the revised NPRM to the Federal Register for publication; next week, maybe….

Wednesday, October 1, 2025

EPA Sends RMP Revision NPRM to OMB

Yesterday the OMB’s Office of Information and Regulatory Affairs announced that it had received a notice of proposed rulemaking from the EPA on “Accidental Release Prevention Requirements: Risk Management Programs Under the Clean Air Act; Common Sense Approach to Chemical Accident Prevention”. This rulemaking is almost certainly a response to the latest program final rule published on March 11th, 2024.

According to the listing for this rulemaking in the Spring 2025 Unified Agenda:

“The U.S. Environmental Protection Agency (EPA) is initiating a new rulemaking to reconsider the current Risk Management Program (RMP) rule requirements. The agency is providing notice of this proposed rulemaking, which will align with agency priorities to ensure clean air, land, and water for every American; restore American energy dominance; and promote cooperative federalism and cross-agency partnership while reducing regulatory burden on facilities.”


Thursday, September 25, 2025

Review – EPA Publishes RMP 30-day ICR Renewal Notice – 9-25-25

Today the EPA published a 30-day information collection request (ICR) renewal notice in the Federal Register (90 FR 46196-46197) for “Risk Management Program Requirements and Petitions To Modify the List of Regulated Substances Under Section 112(r) of the Clean Air Act (Renewal)”. The 60-day ICR renewal notice was published on April 17th, 2025. No programmatic changes are being reported to the ICR, but the burden estimate has changed.

 

Today’s notice explains the reason for the change in burden estimate:

“There is decrease of 36,336 hours in the total estimated respondent burden compared with the ICR currently approved by OMB. Two primary reasons account for this decrease in burden. First, the burden varies from one ICR renewal to the next due to different resubmission deadlines based on the sources' RMP re-submission deadlines [based upon a five-year cycle instead of the ICR’s three-year cycle] and other regulatory deadlines. Therefore, the burden changes each year depending on how many sources must submit their RMP and comply with certain prevention program requirements. Second, the number of sources subject to the regulations fluctuates regularly and is slightly lower than in the previous ICR (12,074 vs. 12,341 sources) due to the net change in new sources minus deregistered sources, as well as a lower number of new facilities anticipated to become subject to the RMP requirements during the three-year clearance period.”

Public Comments

The EPA is soliciting public comments on this ICR notice. Comments may be submitted via the Federal eRulemaking Portal (www.regulation.gov: Docket # EPA-HQ-OEM-2015-0725). Comments should be submitted by October 27th, 2025.

 

For more information about today’s notice, see my article at CFSN Detailed Analysis - https://patrickcoyle.substack.com/p/epa-publishes-rmp-30-day-icr-renewal - subscription required.

Tuesday, September 26, 2023

EPA Sends Accidental Release Final Rule to OMB

Yesterday, the OMB’s Office of Information and Regulatory Affairs (OIRA) announced that it had received a final rule from the EPA on “Accidental Release Prevention Requirements: Risk Management Program Under the Clean Air Act; Safer Communities by Chemical Accident Prevention”. The EPA published [removed from paywall] the notice of proposed rulemaking (NPRM) for this action on August 31st, 2022.

According to the listing for this rulemaking in the 2023 Spring Unified Agenda:

“On August 31, 2022, the Environmental Protection Agency (EPA) published proposed amendments to its Risk Management Program (RMP) regulations as a result of Agency review. The proposed revisions included several changes and amplifications to the accident prevention program requirements, enhancements to the emergency preparedness requirements, increased public availability of chemical hazard information, and several other changes to certain regulatory definitions or points of clarification. Such amendments seek to improve chemical process safety; assist in planning, preparedness, and responding to RMP-reportable accidents; and improve public awareness of chemical hazards at regulated sources. EPA plans to publish the final rule in 2023.”

Wednesday, August 31, 2022

Review - EPA Publishes RMP Accidental Chemical Release NPRM

Today the EPA published a notice of proposed rulemaking (NPRM) in the Federal Register (87 FR 53556-53616) for Accidental Release Prevention Requirements: Risk Management Programs Under the Clean Air Act; Safer Communities by Chemical Accident Prevention. This is the rulemaking for which the EPA published an initial 60-day ICR notice earlier this week. The proposed revisions to the RMP regulations include several changes and amplifications to the accident prevention program requirements, enhancements to the emergency preparedness requirements, increased public availability of chemical hazard information, and several other changes to certain regulatory definitions or points of clarification.

Overview

The EPA provides a broad overview of the intent of the regulation revisions in the preamble to the rule. It provides a discussion of each of the following areas of concern:

Prevention Program,

Emergency Response, and

Areas of Technical Clarification

Public Comments

The EPA is soliciting public comments on this NPRM. Comments may be submitted via the Federal eRulemaking Portal (www.Regulations.gov; Docket # EPA-HQ-OLEM-2022-0174). Comments need to be submitted by October 31st, 2022. I expect that there will be a number of requests for an extension of that time.

For more details about the topics that are covered in this NPRM, see my article at CFSN Detailed Analysis - https://patrickcoyle.substack.com/p/epa-publishes-rmp-accidental-chemical - subscription required. I plan on more detailed coverage of the details of this rulemaking as part of the preparation of my comments for consideration by the EPA.

Sunday, August 28, 2022

EPA Publishes 60-day ICR Notice for RMP Revisions

The EPA published a 60-day information collection request notice (ICR) in Monday’s (available on line yesterday) Federal Register (87 FR 52764-52765) for a new ICR for “Accidental  Release Prevention Requirements: Risk Management Programs Under Section 112(r) of the Clean Air Act, as Amended; Safer Communities by Chemical  Accident Prevention”.

The ICR notice does not provide any details about the proposed changes to the RMP regulations beyond noting:

“The proposed revisions seek to improve chemical process safety, assist in planning, preparedness, and responding to RMP accidents, and improve public awareness of chemical hazards at regulated sources. To accomplish this, these proposed provisions include several changes to the accident prevention program requirements, enhancements to the emergency preparedness requirements, increased public availability of chemical hazard information, and several other changes to certain regulatory definitions or points of clarification.”

The notice does provide the following burden estimate information without any supporting explanation:

• Estimated number of respondents - 14,226,

• Frequency of response – on occasion,

• Estimated hourly response burden - 797,642 hours (per year)

• Estimated burden cost - $79,248,522

EPA is soliciting public comments on the ICR. Comments can be submitted via the Federal eRulmaking Portal (www.Regulations.gov; Docket # EPA-HQ-OLEM-2022-0174). Comments should be submitted by October 28th, 2022.

Commentary

I suspect that this ICR will be supporting an EPA notice of proposed rulemaking (NPRM) that was recently approved by the OMB’s Office of Information and Regulatory Affairs. That NPRM has not yet been published in the Federal Register, but there is a page on the EPA website the outlines the rulemaking and provides a link to a pre-publication version of the NPRM.

Typically, these initial ICR requests supporting new rulemakings are included in the NPRM. It will certainly be difficult for anyone to intelligently comment on this ICR notice until the NPRM is published. The pre-publication version of the NPRM does include such a section on pages 188-9, but it does not provide any additional information about how the EPA arrived at these burden estimates numbers. I will not be submitting a copy of this post complaining about that lack of information, as I do not expect that either the EPA or OIRA will do anything to correct the issue. Part of the reason for that is that it is too early in the regulatory process for the estimates to have any real meaning.

Saturday, August 13, 2022

OMB Approves EPA RMP Release Prevention NPRM

Yesterday the OMB’s Office of Information and Regulatory Affairs (OIRA) announced that it had approved a notice of proposed rulemaking from the EPA on “Accidental Release Prevention Requirements: Risk Management Program Under the Clean Air Act; Retrospection”. According to the abstract in Spring 2022 Unified Agenda listing for the rulemaking:

“The Environmental Protection Agency (EPA) is considering revising the Risk Management Program (RMP) regulations, which implement the requirements of section 112(r)(7) of the 1990 Clean Air Act amendments. The RMP requires facilities that use listed extremely hazardous substances above specified threshold quantities to develop a Risk Management Plan. The EPA is reviewing the RMP rule in accordance with Executive Order 13990: Protecting Public Health and the Environment and Restoring Science to Tackle the Climate Crisis, which directs federal agencies to review existing regulations and take action to address the Administration’s priorities, including bolstering resilience to the impacts of climate change and prioritizing environmental justice.”

We are likely to see the NPRM published this coming week.

Sunday, January 22, 2017

PSM Covered Chemical Facilities National Emphasis Program

Earlier this week the Occupational Health and Safety Administration (OSHA) published guidelines for the implementation of a new chemical facilities national emphasis program (NEP). The guidelines replace those issued in 2011 for a similar NEP.

There are two interesting programmatic changes in the new NEP. First, OSHA is expanding the list of eligible EPA’s Risk Management Program facilities that will be included in the Process Safety Management (PSM) NEP inspection list from just Program 3 facilities to facilities from Programs 1, 2 and 3. Finally, the NEP encourages OSHA inspectors to review reports submitted for the RMP to familiarize themselves with facility processes before the inspection. Both of these changes are almost certainly an outgrowth of chemical safety program coordination requirements from Obama’s Chemical Safety and Security Executive Order (EO 13650).


Wednesday, December 21, 2016

OMB Approves EPA Chemical Safety Final Rule

Yesterday the OMB’s Office of Information and Regulatory Affairs (OIRA) announced that they had approved a final rule from the EPA implementing changes to the Clean Air Act regulations; the “Modernization of the Accidental Release Prevention Regulations under Clean Air Act”. This rule addresses changes to the Risk Management Program identified as a result of the President’s EO 13650 review of chemical safety and security programs. The notice of proposed rulemaking was published in March of this year. I did a series of blog posts about that NPRM.

This rule will certainly be included in any list of accomplishments of the Obama Administration; whether or not it withstands congressional review in the 115th Congress. For better or worse this will be a signature piece of chemical safety regulation.


It will be interesting to see if the EPA tried to craft a rule that would withstand that review or whether they went with a straight implementation of the NPRM. I suspect the later, given the surprising (in most quarters) election of Donald Trump instead of Hillary Clinton to head the next administration. Clinton would have been expected to veto any congressional review negating this rule.

Monday, October 3, 2016

New EO 13650 Chemical Safety Documents

Last week the Occupational Safety and Health Administration (OSHA) updated their “Actions to Improve Chemical Facility Safety and Security” web site with a notice that EO 13650 Working Group had completed a number of new initiatives. Those initiatives included:

• The Working Group published Executive Order 13650 Regulatory Programs Overview
• The Working Group developed the Regulatory Frequent or Critical Violations resource
• OSHA and EPA published Fact Sheet: The Importance of Root Cause Analysis During Incident Investigation
• OSHA published Fact Sheet: The Use of Metrics in Process Safety Management (PSM) Facilities
• OSHA and EPA published the Process Safety Management and Risk Management Plan Comparison Tool

The links in that notice all go to the same place, the EO 13650 “Completed Actions: Modernizing Policies and Regulations” web page. That page further provides links to the following useful fact sheets and program information:



There is also a link to the EPA’s Substance Registry Services web page. This page allows for a single source search capability for a wide variety of Federal resources about chemical health, safety and security information for by chemical name or CAS number.

Thursday, February 25, 2016

OMB Approves EPA RMP NPRM

Yesterday the OMB’s Office of Information and Regulatory Affairs (OIRA) announced that it had approved the EPA’s notice of proposed rulemaking (NPRM) on Modernization of the Accidental Release Prevention Regulations Under Clean Air Act. The NPRM was submitted to OMB in December of last year and is related to the chemical safety and security executive order (EO 13650) issued in 2013.

The Unified Agenda (UA) listing for this rulemaking abstract explains that the rulemaking:

“In response to Executive Order 13650, the EPA is considering potential revisions to its Risk Management Program regulations and related programs. The Agency may consider the addition of new accident prevention or emergency response program elements, and/or changes to existing elements, and/or other changes to the existing regulatory provisions.”

The UA entry claims the Clean Air Act Section 112(r)(7) {42 USC 7412(r)(7)} as the legal basis for this rulemaking which forms the basis for the EPA’s risk management program (RMP). Limiting the legal basis for the rulemaking to sub-paragraph (7) suggests that the following areas for changes suggested in EO 13650 will not be included in this rulemaking:

• General duty clause {§7412(r)(1)};
• List of substances upon which RMP is based {§7412(r)(3)};
• RMP fuel exemption {§7412(r)(4)(b)}; or
• Chemical Safety Board {§7412(r)(6)};

As would be expected, industry has taken a great deal on interest in this rulemaking; going all the way back to their participation in EO 13650 listening sessions and responding to the EPA’s EO 13650 request for information. In just the last couple of weeks there have been a number of meetings at OIRA between a wide variety of groups and the EPA. The OIRA web site provides a listing of those meetings (NOTE: the names listed below are the meeting requestor names, the links provide more details about whom participated in the meetings):

SOCMA;
AF&PA;
AFPM;
CSAG


I expect that we will see this NPRM published in the Federal Register later this week.

Tuesday, December 22, 2015

EPA Sends Accidental Release NPRM to OMB

Yesterday the OMB’s Office of Information and Regulatory Affairs announced that it had received from the EPA a notice of proposed rulemaking (NPRM) to modernize the accidental release prevention regulations under Clean Air Act. The listing for this rulemaking (RIN: 2050-AG82) in the Fall 2015 Unified Agenda makes it clear that this is being initiated in response to the President’s Executive Order on Improving Chemical Facility Safety and Security (EO 13650).

While the EO is specifically mentioned in the Unified Agenda listing, the EPA’s 2014 request for information (RFI) on their Risk Management Program (almost certainly to be addressed in this NPRM) supporting that EO is not mentioned. We could still see that RFI mentioned in the Preamble to the NPRM (and I really suspect that we will), but I suspect that it was not mentioned in the Unified Agenda is that the RFI was much more wide-ranging in its program coverage than the coverage of this rulemaking.

In identifying the legal basis {42 USC 7412(r)(7)} for this rulemaking, the EPA has made it clear that they are only going to address the RMP regulations pertaining to “release prevention, detection, and correction requirements”. Since the list of covered chemicals triggering the RMP status for facilities is provided under §7412(r)(3), it does not appear that this rulemaking will include any changes to that list.

It also appears that two other potential RMP modifications strongly suggested by public comments to the RFI will not appear in this rulemaking. Those are the inclusion of inherently safer technology (IST) standards based upon the General Duty Clause of §7412(r)(1) or expanding the off-site consequence information sharing requirements of §7412(r)(7)(H).


It will be interesting to see how long this NPRM takes to wend its way through the OIRA process. I expect that it will be months (at least) before this NPRM is published. If RMP program revisions are too controversial it is unlikely that this NPRM will make it through to a final rule before the end of the Obama Administration in January of 2017. This may argue for a more moderate update of the regulations that could possibly get through the regulatory process next year. Otherwise, the ultimate fate of this rulemaking would rest with the on-coming President.

Saturday, August 2, 2014

EPA RMP RFI Published

Earlier this week the Environmental Protection Agency’s request for information (RFI) for potential improvements to their Risk Management Program (RMP) was published in the Federal Register (79 FR 44603-44633). The lengthy document marks the official beginning of the process to revise the RMP regulations. It was initiated as part of the response of the EPA to President Obama’s Executive order on Improving the Safety and Security of Chemical Facilities (EO 13650).

The RMP-RFI identifies various areas of the RMP program that might be changed in the rulemaking process. At this point in the rulemaking process EPA has not identified any specific rule changes. Rather it has identified a number of areas of potential change along with a brief look at some of the alternatives that might be considered as part of the rulemaking process. It is seeking to establish a more form dialog with the public and the regulated community about how these potential changes could be most effectively implanted.

OSHA RFI Overlap

OSHA was required to publish their RFI for their chemical safety program, the Process Safety Management (PSM) program, much earlier in the EO 13650 process. Since both of these regulatory programs look at chemical safety issues (EPA from a protection of the community perspective and OSHA from a protection of the worker point of view) there is a certain amount of overlap in the two programs. This means that there will likely be overlaps in the program improvement process as well.

The EPA document identifies seven areas where responses to the OSHA RFI may be applicable to future changes in the RMP program. They include:


RMP Specific Areas of Interest

In addition to these seven areas that are at least partially addressed in the earlier OSHA PSM-RFI, there are eleven areas where EPA is seeking public and industry input on potential changes to the RMP regulations. They are:


Public Comments


The EPA is soliciting public comments on this RFI. Comments may be submitted via the Federal eRulemaking Portal (www.Regulations.gov; Docket # EPA-HQ-OEM-2014-0328). Comments should be submitted by October 29th, 2014.

Friday, July 25, 2014

OMB Approves EPA RMP RFI

As I suggested last night, the OMB announced that it had approved the EPA’s request for information concerning potential changes to their Risk Management Program. This is being reported as being a ‘Notice’ not a ‘Pre-rule’ meaning that an advance notice of proposed rulemaking could still be expected to be part of any rulemaking process arising out of this action.


It won’t be until later today that we know whether or not this notice will be published in Monday’s Federal Register, though I fully expect that it will be.

Sunday, May 25, 2014

EPA Submits RMP RFI Notice to OMB

On Thursday the Environmental Protection Agency submitted a notice to the OMB’s Office of Information and Regulatory Affairs (OIRA) for approval concerning a Risk Management Program request for information. I would assume that this is related to the requirements of §6(a)(iii) of the President’s Executive order on Increasing Chemical Safety and Security (EO 13650). That sub-paragraph requires that the Chemical Safety and Security Working Group to “develop a plan for implementing practical and effective improvements to chemical risk management identified pursuant to subsections (a)(i) and (ii) of this section.”


It will be interesting to see how long this takes to get out of the OMB. Depending on how politically sensitive the recommendations made in the notice actually are this may happen after Election Day in November.

Wednesday, January 8, 2014

EO 13650 §6(a) RFI – EPA Improvements

This is another in a series of posts addressing the recent request for information (RFI) from the EO 13650 Working Group. That RFI addressed requirements in §6(a) of the Improving Chemical Safety and Security Executive Order (EO 13650) for the Working Group to “develop options for improved chemical facility safety and security that identify improvements to existing risk management practices through agency programs, private sector initiatives, Government guidance, outreach, standards, and regulations”. Earlier posts in the series include:


EPA Accomplishments

The RFI addresses EPA accomplishments in chemical safety regulation in two principal areas; Emergency Planning and Community Right to Know Act (EPCRA) and their Risk Management Program (RMP).

At the community level EPCRA ensures that local fire departments, the agency most likely to respond to chemical emergencies, get the needed information to properly respond to a chemical emergency. The RFI notes (pg 4): “Local fire departments receive this information and should [emphasis added] use it to understand the chemical present at facilities in their community and what to do to respond to an accident at the facility.” The EPA has no legal authority to influence or evaluate the community planning process.

The RFI also addresses the availability of the chemical safety information for the public, stating that: “Additionally, the information about chemicals in the community is made available to the public.” This is technically true, but since 9-11 this information, while available at ‘local’ EPA reading centers, is not available from the EPA on the internet. Many community activist organizations, however, have stepped in and placed the information on their web sites.

The RMP program addresses chemical process safety with the emphasis on preventing process upsets or accidents from affecting the local public. The RFI notes that: “EPA conducts chemical plant safety inspection and enforcement efforts at covered facilities based upon this rule.” It does not address, however, how frequently such inspections are actually done with the limited inspection staff available to the EPA or its allied State agencies.

Suggested Areas for Improvements

EPA has identified 7 categories of areas for improvement (pgs 4-5):


• Updating the list of regulated substances;
• Exploring options for improving coverage of reactive substances, reactivity hazards, and explosive chemical hazards;
• Expanding inspector training to include best practices and improve chemical safety beyond regulatory requirements;
• Further enhancing EPA software tools for emergency responders (e.g., the suite of software products called Computer Aided Management of Emergency Operations (CAMEO));
• Evaluating the implementation of best practices and lessons learned such as the “safety case” regulatory model to reduce risk in complex industrial processes;
• Identifying ways to use safer alternatives as mechanisms to reduce chemical risk; and
• Evaluating opportunities for increasing worker involvement and labor-management cooperation in hazard investigations.

Only one of these categories applies to the EPCRA program; the improvements to CAMEO. All of the remainder deal with RMP issues. Part of the reason for that is that Federal agencies are greatly restricted in the requirements that they can place on State and local agencies for fear of establishing ‘unfunded mandates’ that the local jurisdictions cannot afford to implement.

One area that both EPA programs fail to address is the issue of chemical ‘accidents’ caused by deliberate actions. While DHS clearly has the responsibility of preventing terrorist attacks on facilities, that responsibility does not currently extend to preventing actions by disgruntled employees or contractors. Additionally, the response to or mitigation of the consequences of chemical releases from such incidents is not within the area of expertise found within DHS. The extent of the area affected by a deliberate release can be much greater than the current ‘worst case scenario’ planning required under EPCRA.

Some Suggestions

While the CSB has been calling for EPA to cover reactive chemical hazards for more than a decade now, there is no clear consensus of how the agency is supposed to define such potential hazards, much less regulate them. Probably the most hazardous of these reactions, as a general class, are the self-accelerating decomposition reactions (SADR). If EPA were to initially restrict itself to requiring chemical manufacturing facilities to identify potential SADR reactions and methods to limit reaching the critical process upsets (usually temperature) that start such reactions, it will have gone a long way to reducing community risk from reactivity hazards.

The biggest potential improvement to EPCRA (short or regulating the planning activities of State and local agencies which clearly will not happen) would be to have an active requirement for covered facilities to document response drill activities that include local emergency response personnel. That way the regulatory onus will be placed on the facilities that EPA can regulate.

To get around the problem of a too small inspection force (Congressional action would be needed to significantly expand it, and Congressional action is beyond the scope of the President’s EO) the EPA could require RMP covered facilities to submit an annual report on their drill activities in support of the EPCRA drill activity I’ve described above. This would not necessarily ensure the quality of such drills, but at least an effort would be made at most covered facilities.

Public Comments

This is a reminder that the whole purpose of this RFI is to get public feedback on these proposed ideas. The RFI requests the public to respond to these specific proposals for areas of improvement. That response should address the following (pg 9):

• Examples of where implementation of the same or similar options has been successful;
• Information or data that would characterize the positive impacts the options might have, including additional benefits;
• Potential limitations or unintended consequences of the options described;
• Methods for implementing the options, including methods for potentially increasing benefits or reducing costs; or
• Alternatives to the options that could achieve substantially the same result.


Comments need to be submitted by March 31st, 2014. They may be submitted via the Federal eRulemaking Portal (www.Regulatons.gov; Docket #OSHA-2013-0026). This Docket is now operational.

Sunday, August 25, 2013

Reader Email – Reactive Chemistry

I received an interesting email from a reader, Jim, this week about my earlier posting on reactive chemistry and the President’s executive order on “Improving Chemical Facility Safety and Security” (EO 13650). He pointed out a much more common problem of reactive chemistry that I had overlooked that could be considered by the Chemical Facility Safety and Security Working Group while addressing the requirements of §6(c).

Incompatible Chemicals

The reactive chemicals that the reader addresses is the most basic type of chemical hazard, incompatible chemicals; chemicals that because of their most basic nature should not be allowed to come into contact with each other outside of the most controlled chemical process. We are talking things as basic and acids and bases, oxidizers and flammables, and monomers and initiators.

I missed this in my earlier discussion because to me, as chemical professional, this is the most basic component of chemical safety that I almost don’t consciously think about this as an issue. Which is, of course, why it is such a common problem. To be fair, every process hazard analysis (PHA) that I have ever participated in has addressed this issue for the chemicals under review. Jim suggests that the review should be extended to all chemicals at the facility that could come into physical contact with one another.

Reactivity Matrix

Jim suggests the establishment of a reactivity matrix. In its simplest form this would be a spread sheet listing of every chemical in the facility. Each chemical would be listed once on both the horizontal and vertical axis of the spread sheet. At each intersecting cell an entry would be placed that would describe the consequences of mixing the two chemicals. The listing would be (my terms not Jim’s):

• No reaction – quality issues are not a safety consideration;
• To be Avoided – A reaction occurs but, no heat or gasses are evolved, no toxic byproducts are produced, and the resulting material would not be hazardous waste;
• Administrative Controls Required – Minimal heat or non-flammable gasses may be evolved, but not enough to raise pressure in a sealed container with 5% headspace by 1 psig, toxic byproducts may be produced but do not require an increase in personal protective equipment to protect employees against exposure when handling, or waste may require disposal as hazardous waste; or
• Physical Controls Required – Will evolve heat or gasses that will raise pressure in a sealed container with 5% headspace by more than 1 psig, will evolve flammable gasses, or will produce toxic byproducts that will require an increase in personal protective equipment to handle.

Administrative controls are procedures and policies that control when and where such mixing of chemicals may take place. Any reaction requiring administrative controls should require that a HAZOP be performed to review and document those controls.

Physical controls are devices that prevent or control the mixing of the chemicals involved. Any reaction requiring physical controls should require that a PHA be performed to review and document those controls.

Information Availability

Jim makes the point that for most chemical combinations there will be no need for any basic research to take place to make a determination what the reaction label would be for most common chemicals. The information is generally available in the chemical literature. Unfortunately, there are many facilities that use dangerous chemicals that do not have anyone on staff qualified to conduct and interpret a literature search in this area.

A relatively simple and low cost alternative would be to have a research organization like NIST publish a database covering the most common industrial chemicals in use in the United States. The database could be set up to produce a matrix spread sheet by simply selecting the various chemicals that a facility had on site. The facility would only have to fill in the blanks for any chemicals or combination of chemicals not found in the database.

PSM or RMP or CFATS

Which federal agency would be responsible for enforcing this matrix? Well it would depend on the degree of hazard produced by the reactions. Facilities with reactions in only the first two categories (‘No Reaction” and ‘To Be Avoided’) would not generally be regulated for the chemical reactivity matrix. Facilities that have reactions that fall into the last two categories (‘Administrative Controls Required’ or ‘Physical Controls Required) would be required to do a worst case scenario analysis. If that analysis shows no off-site hazards (beyond disposal of hazardous waste) then PSM would be the only regulations addressing the reactivity matrix that the facility would be concerned with. If there were potential off-site consequences the RMP program would be involved and the CFATS people (keeping in mind the existing exemptions) would be notified so that a risk of terrorist attack based upon the reactivity matrix could be assessed.

Major Political Problem

While this all sounds very simple, there is a serious political impediment to this being adopted. We routinely accept chemical reaction risks in our everyday lives. In our kitchens we store incompatible chemicals under the sink, ammonia cleaners and bleach, peroxide and rubbing alcohol being the two common examples. Will every household have to conduct a HAZOP when they buy these materials? Not likely. We use pool chemicals that will violently react and produce chlorine gas. Will every pool cleaning company have to have people on staff to conduct a PHA? It would shut most of them down. Hell, even Mentos® and Coca-Cola® would be regulated under this scheme.

This is one of the reasons that regulators have been so reluctant to try to add reactive chemicals to their chemical safety programs. How do you define realistic safety programs that do not unnecessarily interfere with how people live their lives? At what level in the supply chain should chemical safety controls come into play? Certainly not at the consumer level for all but the most serious hazards. Will the local grocery store have to implement physical controls to prevent the mixing of cleaners? Will the regional warehouse?  These are all political questions, not safety questions, that will have to be addressed.

One way around this is to apply the chemical reaction matrix requirement only to current PSM and RMP covered facilities. This would certainly expand the scope of the current rules, but would not bring any new facilities into the regulatory scheme. This would probably not have any quantum leap in chemical facility safety, but it would cause at least some facilities to take a harder look at chemical reactivity and that would certainly be a good thing.


In any case, this is one approach that the Working Group could take in addressing the requirements for their November 5th review of reactive chemistry required by §6(c) of EO 13650.

Wednesday, August 7, 2013

EO 13650 – The Clock Starts Ticking

The President’s newest Executive Order, Improving Chemical Facility Safety and Security (EO 13650) was published in today’s Federal Register (78 FR 48029-48033). There are large number of deadlines listed in this EO. I’ll put some dates to the deadlines.

45 Days – September 21st, 2013

The Working Group shall deploy a pilot program, involving the EPA, Department of Labor, Department of Homeland Security, and any other appropriate agency, to validate best practices and to test innovative methods for Federal interagency collaboration regarding chemical facility safety and security.

90 Days – November 5th, 2013

The Attorney General, through the head of the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF), shall assess the feasibility of sharing data related to the storage of explosive materials with SERCs, TEPCs, and LEPCs.

The Secretary of Homeland Security shall assess the feasibility of sharing Chemical Facility Anti-Terrorism Standards (CFATS) data with SERCs, TEPCs, and LEPCs on a categorical basis.

The Working Group shall consult with the Chemical Safety Board (CSB) and determine what, if any, changes are required to existing memorandums of understanding (MOUs) and processes between EPA and CSB, ATF and CSB, and the Occupational Safety and Health Administration and CSB for timely and full disclosure of information.

The Working Group shall develop an analysis, including recommendations, on the potential to improve information collection by and sharing between agencies to help identify chemical facilities which may not have provided all required information or may be non-compliant with Federal requirements to ensure chemical facility safety. 

The Working Group shall develop options for improved chemical facility safety and security that identifies improvements to existing risk management practices through agency programs, private sector initiatives, Government guidance, outreach, standards, and regulations

The Secretary of Homeland Security, the Secretary of Labor, and the Secretary of Agriculture shall develop a list of potential regulatory and legislative proposals to improve the safe and secure storage, handling, and sale of ammonium nitrate and identify ways in which ammonium nitrate safety and security can be enhanced under existing authorities.

The Administrator of EPA and the Secretary of Labor shall review the chemical hazards covered by the Risk Management Program (RMP) and the Process Safety Management Standard (PSM) and determine if the RMP or PSM can and should be expanded to address additional regulated substances and types of hazards.

The EPA and the Department of Labor shall develop a plan, including a timeline and resource requirements, to expand, implement, and enforce the RMP and PSM in a manner that addresses the additional regulated substances and types of hazards.

The Secretary of Homeland Security shall identify a list of chemicals, including poisons and reactive substances, that should be considered for addition to the CFATS Chemicals of Interest list.

The Secretary of Labor shall identify any changes that need to be made in the retail and commercial grade exemptions in the PSM Standard.

The Secretary of Labor shall issue a Request for Information designed to identify issues related to modernization of the PSM Standard and related standards necessary to meet the goal of preventing major chemical accidents

135 Days – December 20th, 2013

The Working Group shall develop a plan to support and further enable efforts by State regulators, State, local, and tribal emergency responders, chemical facility owners and operators, and local and tribal communities to work together to improve chemical facility safety and security.

180 Days – February 3rd, 2014

The Working Group shall produce a proposal for a coordinated, flexible data-sharing process which can be utilized to track data submitted to agencies for federally regulated chemical facilities, including locations, chemicals, regulated entities, previous infractions, and other relevant information. 

The Working Group shall identify and recommend possible changes to streamline and otherwise improve data collection to meet the needs of the public and Federal, State, local, and tribal agencies (including those charged with protecting workers and the public), consistent with the Paperwork Reduction Act and other relevant authorities, including opportunities to lessen the reporting burden on regulated industries. 

The Working Group shall engage key stakeholders to discuss the risk management improvement options identified by the Working Group and other means to improve chemical risk management.

270 Days – May 4th, 2014

Chemical Facility Safety and Security Working Group shall provide a status report to the President through the Chair of the Council on Environmental Quality and the Assistant to the President for Homeland Security and Counterterrorism.

The Working Group shall create comprehensive and integrated standard operating procedures for a unified Federal approach for identifying and responding to risks in chemical facilities (including during pre-inspection, inspection execution, post-inspection, and post-accident investigation activities), incident reporting and response procedures, enforcement, and collection, storage, and use of facility information.

The Working Group shall develop a plan for implementing practical and effective improvements to chemical risk management.

Communications

It will be interesting to see how well the various Departments do with meeting their deadlines and with communicating with the public and the regulated community on their progress.
 
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